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Size distribution of the secondary organic aerosol particles from the photooxidation of toluene


HAO Li-qing , WANG Zhen-ya , HUANG Ming-qiang , PEI Shi-xin , YANG Yong , ZHANG Wei-jun

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Received March 21, 2005,Revised May 05, 2005, Accepted , Available online

Volume 17,2005,Pages 912-916

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In a smog chamber, the photooxidation of toluene was initiated by hydroxyl radical(OH·) under different experimental conditions. The size distribution of secondary organic aerosol(SOA) particles from the above reaction was measured using aerodynamic particle sizer spectrometer. It was found from our experimental results that the number of SOA particles increased with increasing the concentration of toluene. As the reaction time prolonged, the sum of SOA particles was also increased. After a reaction time of 130 min, the concentration of secondary organic aerosol particles would be kept constant at 2300 particles/cm3. Increasing illumination power of blacklamps could significantly induce a higher concentration of secondary organic aerosol particle. The density of SOA particles would also be increased with increasing concentration of CH3ONO, however, it would be decreased as soon as this concentration was larger than 225.2 ppm. Nitrogen oxide with initial concentration higher than 30.1 ppm was also found to have little effect on the formation of secondary organic aerosol.

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