Terrestrial environment

Sorption of chlorophenols onto fruit cuticles and potato periderm


Yungui Li , Yingqing Deng , Baoliang Chen

DOI:10.1016/S1001-0742(11)60891-7

Received August 10, 2011,Revised September 27, 2011, Accepted , Available online April 06, 2012

Volume 24,2012,Pages 675-681

To better understand the interaction mechanisms of plant surfaces with polar organic compounds, sorption of 4-chlorophenol, 2,4- dichlorophenol, and 2,4,6-trichlorophenol by fruit cuticles (i.e., tomato, apple, and pepper), and potato tuber periderm were investigated. The roles of cuticular components (waxes, cutin, cutan and sugar) on sorption of chlorophenols are quantitatively compared. Cutin and waxes govern the sorption capacity of bulk apple cuticle by hydrophobic interactions. Potato periderm with highest sugar content exhibits the lowest sorption capability for the chlorophenols. With the increase of hydrophobicity (i.e., Kow ) of sorbate, the relative contribution of lipophilic components (wax, cutin and cutan) on total sorption increases, however, the ratios of Koc to Kow decreases due to increasing ionization degree of sorbates.

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