Comparative sorption and desorption behaviors of PFHxS and PFOS on sequentially extracted humic substances
Lixia Zhao , Yifeng Zhang , Shuhong Fang , Lingyan Zhu
,
Zhengtao Liu
DOI:10.1016/j.jes.2014.04.009
Received January 27, 2014,Revised April 11, 2014, Accepted , Available online December 22, 2014
Volume 26,2014,Pages 2517-2525
The sorption and desorption behaviors of two perfluoroalkane sulfonates (PFSAs), including perfluorohexane sulfonate (PFHxS) and perfluorooctane sulfonate (PFOS) on two humic acids (HAs) and humin (HM), which were extracted from a peat soil, were investigated. The sorption kinetics and isotherms showed that the sorption of PFOS on the humic substances (HSs) was much higher than PFHxS. For the same PFSA compound, the sorption on HSs followed the order of HM > HA2 > HA1. These suggest that hydrophobic interaction plays a key role in the sorption of PFSAs on HSs. The sorption capacities of PFSAs on HSs were significantly related to their aliphaticity, but negatively correlated to aromatic carbons, indicating the importance of aliphatic groups in the sorption of PFSAs. Compared to PFOS, PFHxS displayed distinct desorption hysteresis, probably due to irreversible pore deformation after sorption of PFHxS. The sorption of the two PFSAs on HSs decreased with an increase in pH in the solution. This is ascribed to the electrostatic interaction and hydrogen bonding at lower pH. Hydrophobic interaction might also be stronger at lower pH due to the aggregation of HSs.
