Adsorption of benzene, cyclohexane and hexane on ordered mesoporous carbon


Gang Wang , Baojuan Dou , Zhongshen Zhang , Junhui Wang , Haier Liu , Zhengping Hao

DOI:10.1016/j.jes.2014.10.015

Received May 15, 2014,Revised October 06, 2014, Accepted , Available online April 23, 2015

Volume 27,2015,Pages 65-73

Ordered mesoporous carbon (OMC) with high specific surface area and large pore volume was synthesized and tested for use as an adsorbent for volatile organic compound (VOC) disposal. Benzene, cyclohexane and hexane were selected as typical adsorbates due to their different molecular sizes and extensive utilization in industrial processes. In spite of their structural differences, high adsorption amounts were achieved for all three adsorbates, as the pore size of OMC is large enough for the access of these VOCs. In addition, the unusual bimodal-like pore size distribution gives the adsorbates a higher diffusion rate compared with conventional adsorbents such as activated carbon and carbon molecular sieve. Kinetic analysis suggests that the adsorption barriers mainly originated from the difficulty of VOC vapor molecules entering the pore channels of adsorbents. Therefore, its superior adsorption ability toward VOCs, together with a high diffusion rate, makes the ordered mesoporous carbon a promising potential adsorbent for VOC disposal.

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