Alkali resistance promotion of Ce-doped vanadium-titanic-based NH3-SCR catalysts
Zidi Yan , Xiaoyan Shi , Yunbo Yu , Hong He
DOI:10.1016/j.jes.2018.01.024
Received December 18, 2017,Revised January 01, 1900, Accepted January 26, 2018, Available online February 07, 2018
Volume 30,2018,Pages 155-161
The effect of K deactivation on V2O5/WO3-TiO2 and Ce-doped V2O5/WO3-TiO2 catalysts in the selective catalytic reduction (SCR) of NOx by NH3 was studied. Ce-doped V2O5/WO3-TiO2 showed significantly higher resistance to K deactivation than V2O5/WO3-TiO2. Ce-doped V2O5/WO3-TiO2 with K/V = 4 (molar ratio) showed 90% NOx conversion at 350°C, whereas in this case V2O5/WO3-TiO2 showed no activity. The fresh and K-poisoned V2O5/WO3-TiO2 and Ce-doped V2O5/WO3-TiO2 catalysts were investigated by means of in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), NH3-temperature progress decomposition (NH3-TPD), X-ray photoelectron spectroscopy (XPS) and H2-temperature program reduction (H2-TPR). The effect of Ce doping on the improving resistance to K of V2O5/WO3-TiO2were discussed.
