Fine particle-bound PAHs derivatives at mountain background site (Mount Tai) of the North China: Concentration, source diagnosis and health risk assessment
Jinbao Han , Lei Zhao , Shanjun Song , Penghui Li , Jing Liu , Jing Zhang , Lei Wang , Yaqin Ji , Jinpeng Liu , Liqiong Guo
DOI:10.1016/j.jes.2021.02.023
Received August 07, 2020,Revised , Accepted February 19, 2021, Available online March 17, 2021
Volume 33,2021,Pages 77-87
Ten nitrated polycyclic aromatic hydrocarbons (nPAHs) and 4 oxygenated polycyclic aromatic hydrocarbons (oPAHs) in fine particulate matter (PM2.5) samples from Mount Tai were analyzed during summer (June to August), 2015. During the observation campaign, the mean concentration of total nPAHs and oPAHs was 31.62 pg/m3 and 0.15 ng/m3, respectively. Two of the monitored compounds, namely 9-nitro-anthracene (9N-ANT) (6.86 pg/m3) and 9-fluorenone (9FO) (0.05 ng/m3) were the predominant compounds of nPAHs and oPAHs, respectively. The potential source and long-range transportation of nPAHs and oPAHs were investigated by the positive matrix factorization (PMF) method and the potential source contribution function (PSCF) methods. The results revealed that biomass/coal burning, gasoline vehicle emission, diesel vehicle emission and secondary formation were the dominant sources of nPAHs and oPAHs, which were mainly from Henan province and Beijing-Tianjin-Hebei region and Bohai sea. The incremental life cancer risk (ILCR) values were calculated to evaluate the exposure risk of nPAHs and oPAHs for three group people (infant, children and adult), and the values of ILCR were 7.02 × 10−10, 3.49 × 10−9 and 1.41 × 10−8 for infant, children and adults, respectively. All these values were lower than the standard of EPA (Environmental Protection Agency) (<10−6), indicating acceptable health risk of nPAHs and oPAHs.
