Fine particulate matter (PM2.5/PM1.0) in Beijing, China: Variations and chemical compositions as well as sources
Hezhong Tian , Lining Luo , Xiaoxuan Bai , Shuhan Liu , Bobo Wu , Wei Liu , Yunqian Lv , Zhihui Guo , Shumin Lin , Shuang Zhao , Yan Hao , Jiming Hao , Kai Zhang , Aihua Zheng
DOI:10.1016/j.jes.2021.12.014
Received July 12, 2021,Revised , Accepted December 11, 2021, Available online December 27, 2021
Volume 34,2022,Pages 187-198
Particulate matter (i.e., PM1.0 and PM2.5), considered as the key atmospheric pollutants, exerts negative effects on visibility, global climate, and human health by associated chemical compositions. However, our understanding of PM and its chemical compositions in Beijing under the current atmospheric environment is still not complete after witnessing marked alleviation during 2013–2017. Continuous measurements can be crucial for further air quality improvement by better characterizing PM pollution and chemical compositions in Beijing. Here, we conducted simultaneous measurements on PM in Beijing during 2018–2019. Results indicate that annual mean PM1.0 and PM2.5 concentrations were 35.49 ± 18.61 µg/m3 and 66.58 ± 60.17 µg/m3, showing a positive response to emission controls. The contribution of sulfate, nitrate, and ammonium (SNA) played an enhanced role with elevated PM loading and acted as the main contributors to pollution episodes. Discrepancies observed among chemical species between PM1.0 and PM2.5 in spring suggest that sand particles trend to accumulate in the range of 1–2.5 µm. Pollution episodes occurred accompanied with southerly clusters and high formation of SNA by heterogeneous reactions in summer and winter, respectively. Results from positive matrix factorization (PMF) combined with potential source contribution function (PSCF) models showed that potential areas were seasonal dependent, secondary and vehicular sources became much more important compared with previous studies in Beijing. Our study presented a continuous investigation on PM and sources origins in Beijing, which provides a better understanding for further emission control as well as a reference for other cities in developing countries.
